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HC Technology
Methylparaben
Categories:
Personal Care Ingredients

Methylparaben

Alias
Methylparaben / Methyl parahydroxybenzoate / Methyl p-hydroxybenzoate / Methyl 4-hydroxybenzoate / p-Hydroxybenzoic acid methyl ester / 4-Hydroxybenzoic acid methyl ester / Nipagin / Nipagin M
CAS No.
Molecular Formula
C8H8O3
Structure
Methylparaben Chemical Structure
Product Details

Product Overview

Product Summary

Methylparaben (CAS 99-76-3, molecular formula C8H8O3, molecular weight 152.15) is a colorless crystalline or white crystalline powder at room temperature, melting at 125-128°C, with an assay (on dried basis) of 99.0-100.5 and p-hydroxybenzoic and salicylic acid ≤0.10% (see specifications). For solubility, 1 g dissolves in 400 mL of water or 40 mL of warm oil, and it is freely soluble in alcohol, ether and acetone - one of the more water-soluble members of the paraben series. In cosmetic and personal care formulas, published literature reports inhibitory activity against molds and yeasts; it is used as a preservative component, and finished-product shelf life is subject to the buyer's preservative challenge testing, often combined with other preservatives. Whether a specific use is permitted and its use limits follow the current regulations of the target market, and buyers are responsible for confirming compliance.

Usage

Used in cosmetics and personal care as a preservative and antimicrobial agent in formulations; published literature reports inhibitory activity against molds and yeasts. Finished-product shelf life is subject to the buyer's preservative challenge testing. Often used in combination with other preservatives. Whether a specific use is permitted and its use limits follow the current regulations of the target market, and buyers are responsible for confirming compliance.
Applications

Applications by Industry

Water-Based Cosmetic Preservation Systems

Methylparaben dissolves at 1 g in 400 mL of water (see specifications), which makes it easy to incorporate into water-based systems such as toners, gels and lotion bases; timing and dissolution method follow each formula's process, and in cold processing pre-dissolving in a portion of the water phase is recommended. pH fit and preservative performance should be verified in the actual formulation; this page provides no regulatory limit values.

Personal Care & Cleansing Formulas

Shampoos, body washes and hair conditioners are mostly water-based; methylparaben serves as a preservative component and is often combined with other preservatives (see Usage). Blend design is verified by the formulator; buyers can review assay (99.0-100.5) and appearance against the specifications on this page.

Export Compliance Context

Exported cosmetics and personal care products must meet the target market's listing requirements for the preservatives used; whether a specific use is permitted, its use limits and labelling follow the current regulations of the target market, and buyers are responsible for confirming compliance. No limit values are provided on this page.
Specifications

Technical Specifications

Product Specifications
Appearance Colorless crystals or white crystalline powder
Content (on dried basis) % 99.0–100.5
Melting point °C 125–128
Acidity (pH) 4.0–7.0
Chloride (Cl) % ≤0.035
Sulfate (as SO₄) % ≤0.024
Loss on drying % ≤0.50
Residue on ignition % ≤0.10
p-Hydroxybenzoic acid and salicylic acid % ≤0.10
Related substances Pass
Solution appearance Pass
Boiling point °C 198.6
Density g/cm³ 1.46
Refractive index 1.4447
Flash point °C 280
Solubility 1 g dissolves in 400 mL water or 40 mL warm oil; freely soluble in alcohol, ether and acetone; slightly soluble in benzene and carbon tetrachloride
Logistics

Packaging, Storage & Transport

Packaging

25 kg/fiber drum; custom packaging available upon request. Sample arrangements and order quantities can be discussed during inquiry, and regular batches are produced against the order schedule.

Storage

Store sealed in a cool, dry, well-ventilated place; protect from moisture and light

Transport

Transport classification follows the goods transport appraisal report and the carrier's requirements

FAQ

Frequently Asked Questions

How water-soluble is methylparaben, and how is it added?
Per the specifications, 1 g dissolves in 400 mL of water or 40 mL of warm oil, and it is freely soluble in alcohol, ether and acetone. Water-based formulas can dissolve it directly in the water phase; in cold processing, pre-dissolve it in a portion of the water phase or pre-disperse from an alcohol solution to avoid uneven distribution.
What are the assay and key specifications?
Assay (on dried basis) 99.0-100.5, melting point 125-128°C, acidity pH 4.0-7.0, loss on drying ≤0.50%, residue on ignition ≤0.10%, p-hydroxybenzoic and salicylic acid ≤0.10% (see specifications). The product is produced and released against these figures; batch data is confirmed with our sales team during inquiry.
Which preservatives is it combined with?
It is often used with other preservatives; blending the methyl, ethyl, propyl and butyl paraben esters at different ratios is a common practice. Actual blend design is verified by the formulator in the real system.
What is the use limit?
This page does not provide limit values. Permitted preservatives and their use limits in cosmetics follow the current regulations of the target market, and buyers are responsible for confirming compliance; product specifications and packaging can be discussed during inquiry.
What are the common aliases for methylparaben?
Common aliases include methyl p-hydroxybenzoate, Nipagin M and 4-hydroxybenzoic acid methyl ester. The paraben esters carry similar names, so quoting CAS number 99-76-3 in inquiries is recommended.
What are the packaging, storage and transport requirements?
Standard packaging is a 25 kg fiber drum, with custom packaging available. As the more water-soluble member of the paraben series (1 g dissolves in 400 mL of water, see specifications), keep the powder tightly sealed against moisture. Store sealed in a cool, dry, well-ventilated place, protected from moisture and light; transport classification follows the transport identification report and carrier requirements; protect from moisture, sunlight and physical damage. Samples and order quantities can be discussed during inquiry.